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PO-T2T

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PO-T2T

Product Detail

1. Overview

The field of organic light-emitting diodes (OLEDs) is dynamic and rapidly advancing. Among the various materials contributing to this technology, PO-T2T has emerged as a notable contender within the OLED stack. Officially named 2, 4, 6-Tris[ 3-(diphenylphosphinyl) phenyl] 1, 3 , 5-triazine, this electron deficient compound is distinguished by its triazine core and three diphenylphosphinyl groups. Its unique molecular design makes it a valuable material for use in organic electronic applications.

PO-T2T is mainly used as an electron transport/hole blocking or an electron acceptor material in organic electronics.

  • Excellent thermal stability
  • Excellent solubility in toluene, ethanol which helps in the formation of high-quality films
  • Electron-deficient molecule with good electron mobility
  • Good doped to ZnO, ZnMgO
  • Alternative to problematic ZnO, ZnMgO, BPhen, and TPBi

2. Specifications

Product Name

PO-T2T

CAS no.

1646906-26-4

Chemical Formula:

C57H42N3O3P3

Full name:

2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

Molecular weight (g/mol):

909.88 g/mol

Purity:

Sublimed: >99.0%

Physical state:

Solid

Color:

Off-white

Absorption (nm):

lmax 272 (in DCM)

Emission (nm):

lmax 295, 378 (in DCM)

HOMO/LUMO (eV):

HOMO = 7.55 / LUMO = 3.50

Melting Point (°C):

282 - 285

Chemical Structure of 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

Chemical Structure of 2,4,6-Tris[3-(diphenylphosphinyl)phenyl]-1,3,5-triazine

3. Features

  • Exciplex Formation: A key feature of PO-T2T is its ability to form exciplexes, which plays a vital role in advancing OLED technology, and crucial in Thermally Activated Delayed Fluorescence (TADF) OLEDs.

  • Electron Transport Layer (ETL) Functionality: With the electron-deficient characteristics, PO-T2T is widely utilized as a material for electron transport layers. This contributes to the efficient operation and extended lifespan of OLED devices.

  • Improved OLED Performance: By pairing with electron-donating materials, PO-T2T has demonstrated its effectiveness in enhancing critical OLED performance metrics. This includes prolonging device lifetime and lowering driving voltage, ultimately resulting in more energy-efficient OLED systems.

4. Applications

Function in OLEDs

  • Acceptor material layer
  • Electron transport layer (ETL) in luminescent devices/displays
  • Hole blocking layer (HBL)
  • Organic low molecular host

Function in perovskite-based devices

  • Hole blocking layer (HBL) material at a multiplier perovskite-organic composite photodetector
  • Organic semiconductor in radiation-emitting perovskite
  • Organic low-molecular host in radiation-emitting perovskite
  • Antisolvent in the method of perovskite production

Other Functions

  • Electron transfer material in injection layers (EIL) in quantum dots
  • Ink electron transport material
  • Electron transport material in an electro-laser device based on nanorods
  • Transport layer material in organic electronic devices
  • Electron-generating layer in an N-type semiconductor

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